| 微波合成条件下Sm3+对CaS:Eu2+红色发光的增强 |
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| 引用本文： | 张迈生,臧李纳,严纯华.微波合成条件下Sm3+对CaS:Eu2+红色发光的增强[J].材料导报,2001,15(2):70-72. |
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| 作者姓名： | 张迈生 臧李纳 严纯华 |
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| 作者单位： | 1. 中山大学化学与化学工程学院,
2. 北京大学 |
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| 基金项目： | 广东省自然科学基金，国家重点实验室基金，960078，，， |
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| 摘 要： | 首次在微波场作用 下快速合成了类球形亚超细CaS:Sm^3 ,Eu^2 磷光体，平均粒径为240~450nm，系统考察了Sm^3 ,Eu^2 双掺离子在没掺杂浓度时对CaS磷光体荧光性质的影响，并探讨了Sm^3 →Eu^2 之间的能量传递机理。
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| 关 键 词： | 微波合成 钐 铕 掺杂 无机稀土发光材料 硫化钙 类球形 能量传递 红色荧光 磷光体 |
Rapid Synthesis of CaS: Sm3+,Eu2+ Phosphor with Submicron-scale by Microwave Radiation Method |
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| Zhang Maisheng Zang Lina Yan Chunhua.Rapid Synthesis of CaS: Sm3+,Eu2+ Phosphor with Submicron-scale by Microwave Radiation Method[J].Materials Review,2001,15(2):70-72. |
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| Authors: | Zhang Maisheng Zang Lina Yan Chunhua |
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| Abstract: | In this paper,CaS:Sm3+ ,Eu2- phosphor are firstly synthesized by microwave radiation method(MRM).The materials with submicro-scale(300~400nm) have been characterized by XRD,SEM and the fluorescent spectroscopy. It shows the different concentrations of Sm2+ and Eu2+ differently effects on the fluorescent properties. Sm3+ ion may efficiency enhance the red fluorescence of CaS : Eu2+ phosphor since the energy transfer of Sm3+-Eu2+. |
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| Keywords: | rapid synthesis by microwave radiation method sphere submicro-scale energy transfer luminescence |
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