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氧化镍水泥基复合材料热电性能研究
引用本文:肖龙,季涛,廖晓,麻福斌,侯保荣.氧化镍水泥基复合材料热电性能研究[J].新型建筑材料,2019(3):32-35.
作者姓名:肖龙  季涛  廖晓  麻福斌  侯保荣
作者单位:宁波市杭州湾大桥发展有限公司;中国建筑第八工程局有限公司工程研究院;中国科学院海洋研究所海洋环境腐蚀与生物污损重点实验室;青岛海洋科学与技术国家实验室海洋腐蚀与防护开放工作室
基金项目:国家自然科学基金项目(51708541);博士后科学基金(2016M592256)
摘    要:将纳米氧化镍作为热电组份掺入水泥浆中以提高水泥基材料热电性能,研究了纳米氧化镍对水泥基材料热电性能的影响,并分析其作用机理。结果表明,随着纳米氧化镍掺量的增加,水泥基复合材料的Seebeck系数及电导率逐渐增大,当纳米氧化镍掺量为水泥质量的5.0%时,水泥基复合材料的Seebeck系数最大,约为4050μV/℃,远高于碳纤维增强水泥基材料,电导率此时也达到最大,约为6.76×10-5 S/cm,远高于硬化水泥浆试样。

关 键 词:水泥基材料  纳米氧化镍  热电组份  SEEBECK系数  电导率

Thermoelectric property of cement composites with nickel oxide
XIAO Long,JI Tao,LIAO Xiao,MA Fubin,HOU Baorong.Thermoelectric property of cement composites with nickel oxide[J].New Building Materials,2019(3):32-35.
Authors:XIAO Long  JI Tao  LIAO Xiao  MA Fubin  HOU Baorong
Affiliation:(Ningbo Hangzhou Bay Bridge Development Co. Ltd.,Ningbo 315327,China;Engineering Research Institute of China Construction Eighth Engineering Division Co.Ltd.,Shanghai 200122,China;CAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling,Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China;Open Studio for Marine Corrosion and Protection,Qingdao National Laboratory for Marine Science and Technology,Qingdao 266237,China)
Abstract:Nano-nickel oxide was incorporated into cement paste as the thermoelectric component to increase the thermoelectric performance of cement paste. The thermoelectric performance and mechanism of these cement composites were researched in this paper. Results showed that the Seebeck coefficient and conductivity of the cement composite increased with the content of NiO powders. When the NiO content was 5.0%,the maximum Seebeck coefficient of cement composite was tested 4050 μV/℃,which was far higher than that of carbon fiber reinforced cement composite. The maximum electrical conductivity was about 6.76×10^-5 S/cm when the NiO content was 5.0%,which was far higher than that of hardened cement paste.
Keywords:cement composite  nano-nickel oxide  thermoelectric component  Seebeck coefficient  electrical conductivity
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