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铝合金表面超疏水涂层的火焰喷雾热解法制备及其耐蚀性能
引用本文:贾毅,岳仁亮,刘刚,倪勇,杨洁,刘海弟,陈运法.铝合金表面超疏水涂层的火焰喷雾热解法制备及其耐蚀性能[J].功能材料,2012,43(9):1113-1117.
作者姓名:贾毅  岳仁亮  刘刚  倪勇  杨洁  刘海弟  陈运法
作者单位:1. 中国科学院过程工程研究所多相复杂系统国家重点实验室,北京100190/中国科学院研究生院,北京100049
2. 中国科学院过程工程研究所多相复杂系统国家重点实验室,北京,100190
基金项目:中国科学院重大科研装备资助项目
摘    要:采用火焰喷雾热解与表面修饰相结合的方法在铝合金表面制备了具有一定耐蚀性能的超疏水表面。以六甲基二硅氧烷溶液为前驱液,通过火焰喷雾热解方法,首先在铝合金表面沉积SiO2纳米颗粒构建粗糙结构,再以氟硅烷溶液进行表面修饰,获得了具有154.9°静态接触角,滚动角<2°的超疏水表面。通过电化学测试,对比了构筑超疏水表面前后的铝合金样品的耐蚀性能。结果表明沉积层与低表面能物质协同作用,通过对腐蚀性离子的有效隔离,提高了铝合金基体的耐蚀性能。

关 键 词:火焰喷雾热解  超疏水  SiO2  铝合金  耐蚀性能

Flame spray pyrolysis fabricating superhydrophobic coatings on aluminum alloy with its anti-collision property
JIA Yi,YUE Ren-liang,LIU Gang,NI Yong,YANG Jie,LIU Hai-di,CHEN Yun-fa.Flame spray pyrolysis fabricating superhydrophobic coatings on aluminum alloy with its anti-collision property[J].Journal of Functional Materials,2012,43(9):1113-1117.
Authors:JIA Yi  YUE Ren-liang  LIU Gang  NI Yong  YANG Jie  LIU Hai-di  CHEN Yun-fa
Affiliation:1(1.State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China; 2.Graduate University of Chinese Academy of Sciences,Beijing 100049,China)
Abstract:Superhydrophobic coatings were fabricated on aluminum alloy substrate via a method combining flame spray pyrolysis(FSP) and surface modification.The FSP method was utilized to form a multi-scale roughness surface by depositing SiO2 nanoparticles directly on to aluminum alloy substrates.Hexamethyldisiloxane(HMDSO) was used as the SiO2 precursor.The surface structure was altered by adjusting the deposition parameters.The coating after fluoration showed superhydrophobicity with a static contact angle up to 154.9° and a tilt angle smaller than 2°.The superhydrophobic coatings were characterized by SEM and AFM to identify the surface morphology and roughness.The results of electrochemical measurements(electrochemical impedance spectroscopy and polarization curve) showed that anti-corrosion property of aluminum alloy was obviously improved.
Keywords:flame spray pyrolysis  superhydrophobic  aluminum alloy  corrosion resistance
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