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硝基胍发射药燃烧性能的模拟
引用本文:杨栋,赵宝昌,宋洪昌,何秀英. 硝基胍发射药燃烧性能的模拟[J]. 含能材料, 1998, 6(1): 15-18
作者姓名:杨栋  赵宝昌  宋洪昌  何秀英
作者单位:南京理工大学化工学院
摘    要:分析了硝基胍热分解和燃烧的特征,提出了NQ燃烧初期热分解的假设,并推导了NQ发射药的燃速和燃烧速压指数公式。

关 键 词:燃烧动力学 数值模拟 硝基 发射药
收稿时间:1996-07-04

MODELING ON BURNING CHARACTERISTICS OF NITROGUANIDINE PROPELLANT
Yang Dong,Zhao Bao-chang,Song Hong-chang and He Xiu-ying. MODELING ON BURNING CHARACTERISTICS OF NITROGUANIDINE PROPELLANT[J]. Chinese Journal of Energetic Materials, 1998, 6(1): 15-18
Authors:Yang Dong  Zhao Bao-chang  Song Hong-chang  He Xiu-ying
Affiliation:Chemical Coll.,Nanjing Univ.of Science and Technology,Nanjing 210094;Chemical Coll.,Nanjing Univ.of Science and Technology,Nanjing 210094;Chemical Coll.,Nanjing Univ.of Science and Technology,Nanjing 210094;Chemical Coll.,Nanjing Univ.of Science and Technology,Nanjing 210094
Abstract:Thermal decomposition and combustion characteristics of nitroguanidine(NQ) are analysed.The NQ decomposition hypothesis about the primary stage of combustion is proposed,and the burning rate formula and pressure index formula of NQ propellant are derived.The NQ propellant burning characteristics from 0 MPa to 400 MPa are numerically modeled and calculated, result are in good agreement with the experimental data. The accurate calculated results show that the pressure index decreases at the middle and high pressure region with the addition of NQ to the double base propellant.The reason of low pressure index and the possibility of NQ as a burning rate modifier in nitramine (RDX and HMX) propellant are discussed.
Keywords:burning rate  burning rate pressure index  combustion chemical kinetics  combustion mechanism  NQ propellant  numerical modeling.  
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