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Perovskite Solar Cells with ZnO Electron‐Transporting Materials
Authors:Peng Zhang  Jiang Wu  Ting Zhang  Yafei Wang  Detao Liu  Hao Chen  Long Ji  Chunhua Liu  Waseem Ahmad  Zhi David Chen  Shibin Li
Affiliation:1. School of Optoelectronic Information, University of Electronic Science and Technology of China, Chengdu, China;2. Department of Electronic and Electrical Engineering, University College London, London, UK;3. Department of Electrical & Computer Engineering and Center for Nanoscale Science & Engineering, University of Kentucky, Lexington, KY, USA
Abstract:Perovskite solar cells (PSCs) have developed rapidly over the past few years, and the power conversion efficiency of PSCs has exceeded 20%. Such high performance can be attributed to the unique properties of perovskite materials, such as high absorption over the visible range and long diffusion length. Due to the different diffusion lengths of holes and electrons, electron transporting materials (ETMs) used in PSCs play a critical role in PSCs performance. As an alternative to TiO2 ETM, ZnO materials have similar physical properties to TiO2 but with much higher electron mobility. In addition, there are many simple and facile methods to fabricate ZnO nanomaterials with low cost and energy consumption. This review focuses on recent developments in the use of ZnO ETM for PSCs. The fabrication methods of ZnO materials are briefly introduced. The influence of different ZnO ETMs on performance of PSCs is then reviewed. The limitations of ZnO ETM‐based PSCs and some solutions to these challenges are also discussed. The review provides a systematic and comprehensive understanding of the influence of different ZnO ETMs on PSCs performance and potentially motivates further development of PSCs by extending the knowledge of ZnO‐based PSCs to TiO2‐based PSCs.
Keywords:electron transport materials  nanostructures  perovskite solar cells  photovoltaics  zinc oxide
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