A Biopolymer Heparin Sodium Interlayer Anchoring TiO2 and MAPbI3 Enhances Trap Passivation and Device Stability in Perovskite Solar Cells |
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| Authors: | Shuai You Hui Wang Shiqing Bi Jiyu Zhou Liang Qin Xiaohui Qiu Zhiqiang Zhao Yun Xu Yuan Zhang Xinghua Shi Huiqiong Zhou Zhiyong Tang |
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| Affiliation: | 1. National Center for Nanoscience and Technology, Beijing, P. R. China;2. Collaborative Innovation Center of Henan Province for Energy‐Saving Building Materials, Xinyang Normal University, Xinyang, P. R. China;3. Heeger Research and Development Center, School of Chemistry, Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University, Beijing, P. R. China;4. Center for Medical Device Evaluation, China Food and Drug Administration, Beijing, China;5. University of Chinese Academy of Sciences, Beijing, China |
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| Abstract: | Traps in the photoactive layer or interface can critically influence photovoltaic device characteristics and stabilities. Here, traps passivation and retardation on device degradation for methylammonium lead trihalide (MAPbI3) perovskite solar cells enabled by a biopolymer heparin sodium (HS) interfacial layer is investigated. The incorporated HS boosts the power conversion efficiency from 17.2 to 20.1% with suppressed hysteresis and Shockley–Read–Hall recombination, which originates primarily from the passivation of traps near the interface between the perovskites and the TiO2 cathode. The incorporation of an HS interfacial layer also leads to a considerable retardation of device degradation, by which 85% of the initial performance is maintained after 70 d storage in ambient environment. Aided by density functional theory calculations, it is found that the passivation of MAPbI3 and TiO2 surfaces by HS occurs through the interactions of the functional groups (? COO?, ? SO3?, or Na+) in HS with undersaturated Pb and I ions in MAPbI3 and Ti4+ in TiO2. This work demonstrates a highly viable and facile interface strategy using biomaterials to afford high‐performance and stable perovskite solar cells. |
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| Keywords: | heparin sodium interface modification perovskites stability trap passivation |
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