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Electrical properties of alumina films grown on Si at low temperature using catalytic CVD
Authors:Yoh-Ichiro Ogita  Satoshi Ohsone  Fumitaka Sakamoto
Affiliation:a Kanagawa Institute of Technology, 1030 Shimo-Ogino, Atsugi, Kanagawa, 243-0292, Japan
b Thermo Electron K. K. C-2F, 3-9 Moriyacho, Kanagawa-ku, Yokohama, 221-0222, Japan
Abstract:The electrical properties of alumina films formed at substrate temperatures as low as 27 °C using tri-methyl aluminum (TMA) and molecular oxygen (O2) by catalytic chemical vapor deposition (Cat-CVD) have been investigated by capacitance-voltage (C-V), current-voltage (I-V) measurements and X-ray photoelectron spectroscopy (XPS). Substrate temperature dependence of dielectric constant and leakage current of the films has been explained on the basis of deficiency in oxygen. Interface trapping density of the order of 109 ev− 1cm− 2 has been obtained. Angle resolved XPS measurements have revealed that the direct bonding of alumina and Si was realized with very small interface trapping density.
Keywords:Dielectric constant  XPS  Cat-CVD  Al2O3  Interface trapping density  Leakage current  High-k gate
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