Synthesis of amines from higher aliphatic esters,ammonia and hydrogen |
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| Affiliation: | 1. Department of Chemistry, University of South Florida, Tampa, FL 33620, USA;2. Drug Discovery Department, H. Lee Moffitt Cancer Center and Research Institute, 12902 Magnolia Drive, Tampa, FL 33612, USA;3. Department of Oncologic Sciences, College of Medicine, University of South Florida, Tampa, FL 33612, USA;1. Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 106 91 Stockholm, Sweden;1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Key Lab of Science and Technology of Eco-Textile, Ministry of Education, College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China;2. School of Science, Harbin Institute of Technology, Shenzhen 518055, China;3. Shenzhen Bay Laboratory, Shenzhen 518055, China |
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| Abstract: | - 1.1. A study was made of the effect of operational parameters on amination of esters on a fused iron catalyst. Conditions were found to obtain aliphatic amines with a yield of up to 85–86%.
- 2.2. During amination of aliphatic esters both the acid and the alcoholic group of the initial ester take part in the formation of amines.
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