| NH4NO3和NH4ClO4的绝热分解研究 |
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| 引用本文： | 钱新明,傅智敏,张文明,冯长根. NH4NO3和NH4ClO4的绝热分解研究[J]. 含能材料, 2001, 9(4): 156-160 |
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| 作者姓名： | 钱新明 傅智敏 张文明 冯长根 |
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| 作者单位： | 北京理工大学爆炸与安全科学国家重点实验室, |
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| 基金项目： | 国家自然科学基金资助项目（编号：19802004） |
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| 摘 要： | 用加速热量仪研究了硝酸铵和高氯酸铵的热分解过程，得到了它们的绝热分解温度和压力随时间的变化曲线，并分别计算了这两种物质的动力学参数表观活化能和指前因子。
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| 关 键 词： | 硝酸铵 AN 高氯酸铵 AP 绝热分解 加速热量仪 表观活化能 指前因子 ARC |
| 文章编号： | 1006-9941(2001)04-0156-05 |
| 收稿时间： | 2001-05-21 |
| 修稿时间： | 2001-05-21 |
Study on the Thermal Decomposition of Ammonium Nitrate and Ammonium Perchlorate by Accelerating Rate Calorimeter |
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| QIAN Xin-ming,FU Zhi-min,ZHANG Wen-ming and FENG Chang-gen. Study on the Thermal Decomposition of Ammonium Nitrate and Ammonium Perchlorate by Accelerating Rate Calorimeter[J]. Chinese Journal of Energetic Materials, 2001, 9(4): 156-160 |
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| Authors: | QIAN Xin-ming FU Zhi-min ZHANG Wen-ming FENG Chang-gen |
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| Affiliation: | National Key Laboratory for Explosive and Safety Science, Beijing Institute of Technology, Beijing 100081, China;National Key Laboratory for Explosive and Safety Science, Beijing Institute of Technology, Beijing 100081, China;National Key Laboratory for Explosive and Safety Science, Beijing Institute of Technology, Beijing 100081, China;National Key Laboratory for Explosive and Safety Science, Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | The thermal decompositions of ammonium nitrate(AN) and ammonium perchlorate(AP) are investigated by ARC (Accelerating Rate Calorimeter). The curves of thermal decomposition temperature and pressure versus time for the two systems are obtained. There are obvious differences in decomposition characteristic between the two chemicals. The kinetic parameters such as apparent activation energy and pre exponential factor of the thermal decomposition of AN and AP are calculated respectively. |
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| Keywords: | ammonium nitrate ammonium perchlorate adiabatic decomposition accelerating rate calorimeter |
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