| 绿色乳化剂在丙烯酸酯类乳液聚合中的应用研究 |
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| 引用本文： | 黄凯兵,梁巧灵,李文佳,施敏,周洪.绿色乳化剂在丙烯酸酯类乳液聚合中的应用研究[J].功能材料,2011,42(3):414-417. |
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| 作者姓名： | 黄凯兵 梁巧灵 李文佳 施敏 周洪 |
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| 作者单位： | 湖南大学材料科学与工程学院; |
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| 基金项目： | 国家自然科学基金资助项目(50772043) |
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| 摘 要： | 采用预乳化半连续种子乳液聚合工艺制备聚丙烯酸醋类乳液,在聚合过程中以环保的脂肪醇聚氧乙烯醚(AEO-9)、脂肪醇聚氧乙烯醚磺基琥珀酸单酯二钠(A-102)、失水山梨醇油酸酯聚氧乙烯醚(Tween 80)替代传统的烷基酚聚氧乙烯醚(APED)乳化剂,并探讨了不同乳化剂对聚合物乳液粘度、残单量、分子量、稳定性、玻璃化转变温...
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| 关 键 词： | 聚丙烯酸酯类乳液 烷基酚聚氧乙烯醚 绿色乳化剂 残单量 |
A study on the application of green surfactants to polyacrylate emulsion |
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| HUANG Kai-bing,LIANG Qiao-ling,LI Wen-jia,SHI Min,ZHOU Hong.A study on the application of green surfactants to polyacrylate emulsion[J].Journal of Functional Materials,2011,42(3):414-417. |
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| Authors: | HUANG Kai-bing LIANG Qiao-ling LI Wen-jia SHI Min ZHOU Hong |
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| Affiliation: | HUANG Kai-bing,LIANG Qiao-ling,LI Wen-jia,SHI Min,ZHOU Hong(College of Materials Science & Engineering,Hunan University,Changsha 410082,China) |
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| Abstract: | A polyacrylate emulsion was prepared by pre-emulsified technique,adopting semi-continuous seeded emulsion polymerization methods.Choosing environmental friendly alcohol ethoxylates(AEO-9),sulfosuccinic acid alkyl polyoxyethylene monoester disodium salt(A-102) and sorbitan monooleate(Tween 80) instead of traditional alkyl phenol ethoxylates(APEO) as surfactants in polymerization.In this article,the effects of these surfactants on viscosity,residual monomer,molecular weight,stability,glass transition temperat... |
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| Keywords: | polyacrylate emulsion alkyl phenol ethoxylates green surfactants residual monomer |
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