Synthesis and luminescent properties of ZnNb2O6 nanocrystals for solar cell |
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Authors: | Yu-Jen Hsiao Liang-Wen Ji |
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Affiliation: | a National Nano Device Laboratories, Tainan 741, Taiwanb Department of Mechanical Engineering, National Kaohsiung University of Applied Sciences, Kaohsiung 807, Taiwanc Institute of Electro-Optical and Materials Science, National Formosa University, Yunlin 632, Taiwan |
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Abstract: | The phase formation, morphology and luminescent properties of ZnNb2O6 nanocrystals by the sol-gel method were investigated at a lower temperature than that of the traditional solid-state reaction method. The products were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), photoluminescence spectroscopy (PL) and absorption spectra. The activation energy of ZnNb2O6 grain growth is obtained about 18.4 kJ/mol. The diameters of the nanocrystals are in the range of 20-40 nm. The PL spectra excited at 276 nm have a broad and strong blue emission band maximum at 450 nm, corresponding to the self-activated luminescence of the niobate octahedra group NbO6]7−. The optical absorption spectrum of the sample at a calcination temperature of 800 °C has a band gap energy of 3.68 eV. |
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Keywords: | Luminescence Sol-gel preparation Optical materials and properties |
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