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光交联明胶-壳聚糖共混膜制备及性能研究
引用本文:白绘宇,王娟勤,刘晓亚. 光交联明胶-壳聚糖共混膜制备及性能研究[J]. 广东化工, 2010, 37(10): 6-7,26
作者姓名:白绘宇  王娟勤  刘晓亚
作者单位:江南大学化学与材料工程学院,江苏无锡214122;;江南大学化学与材料工程学院,江苏无锡214122;;江南大学化学与材料工程学院,江苏无锡214122;
基金项目:国家重点实验室课题(SKLF-MB-200805)和江南大学自主科研计划资助项目(JUSRP30905)
摘    要:本实验用以聚乙烯醇-苯乙烯基吡啶盐的缩合物(PVA-SbQ)为光敏剂,运用紫外光辐照法以制备交联明胶-壳聚糖共混膜。用傅立叶红外、X-射线衍射方法对膜的结构进行表征,并对膜的力学性能、吸湿率、透光率性能进行研究。研究表明:PVA-SbQ分子与明胶、壳聚糖分子间存在氢键作用,光交联后,共混膜形成网状结构,有效地改善了共混膜的力学性能、吸湿性和紫外屏蔽性能等。

关 键 词:明胶  壳聚糖  PVA-SbQ  光交联  

Study on Preparation and Properties of Photocross-Linked Gel/CS/PVA-SbQ Membrane
Bai Huiyu,Wang Juanqin,Liu Xiaoya. Study on Preparation and Properties of Photocross-Linked Gel/CS/PVA-SbQ Membrane[J]. Guangdong Chemical Industry, 2010, 37(10): 6-7,26
Authors:Bai Huiyu  Wang Juanqin  Liu Xiaoya
Affiliation:(School of Chemical &Material Engineering, Jiangnan University, Wuxi 214122, China)
Abstract:In the experiment, photocross-linked gelatin-chitosan blend membrane was prepared by mixing the solutions of gelatin, chitosan and PVA-SbQ. Its structure was examined by means of FT-IR and XRD. The properties of membrane, such as mechanical property, hygroscopicity and light transmittance had been studied. The results show that: improved properties of the membrane such as mechanical property, hygroscopicity and UV screen property are due to some hydrogen bonding interaction between gelatin, chitosan and PVA-SbQ in the blend membrane and network of exposed membrane.
Keywords:gel  CS  PVA-SbQ: photocross-link  membrane
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