| SO_4~(2-)/ZrO_2固体超强酸催化剂金属离子复合、改性及在乙酰丙酸制备中的研究 |
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| 引用本文： | 李小保,黄秋萍,罗公平,叶菊娣,马跃进. SO_4~(2-)/ZrO_2固体超强酸催化剂金属离子复合、改性及在乙酰丙酸制备中的研究[J]. 广东化工, 2010, 37(10): 244-245,235 |
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| 作者姓名： | 李小保 黄秋萍 罗公平 叶菊娣 马跃进 |
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| 作者单位： | 南京林业大学化工学院,江苏南京210037; |
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| 基金项目： | 南京林业大学科技创新基金（163030025） |
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| 摘 要： | 采用共沉淀法制备了SO42-/ZrO2-Fe2O3和SO42-/ZrO2-Al2O3双金属固体超强酸催化剂,其中SO42-/ZrO2-Fe2O3对葡萄糖水解生成5-羟甲基糠醛的反应有利,而SO42-/ZrO2-Al2O3对5-羟甲基糠醛脱羧生成乙酰丙酸的反应有利。采用沉淀-浸渍法制取两种金属离子改性的SO42-/ZrO2催化剂,该类催化剂对葡萄糖水解制5-羟甲基糠醛和5-羟甲基糠醛脱羧生成乙酰丙酸的反应均有利。
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| 关 键 词： | SO4^2-／ZrO2 改性 乙酰丙酸 |
Study on SO4^2-/ZrO2 Superacids Modified by Complex or Doping Metal ions for Preparation of Levulinic Acid |
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| Li Xiaobao,Huang Qiuping,Luo Gongping,Ye Judi,Ma Yuejin. Study on SO4^2-/ZrO2 Superacids Modified by Complex or Doping Metal ions for Preparation of Levulinic Acid[J]. Guangdong Chemical Industry, 2010, 37(10): 244-245,235 |
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| Authors: | Li Xiaobao Huang Qiuping Luo Gongping Ye Judi Ma Yuejin |
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| Affiliation: | (College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China) |
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| Abstract: | SO4^2-/ZrO2-Fe2O3 and SO4^2-/ZrO2-Al2O3 bimetal superacids were prepared by precipitation, and SO4^2-/ZrO2 superacids modified by doping metal ions were prepared by impregnation. Results show that SO4^2-/ZrO2-Fe2O3 sped the reaction for hydrolysis of glucose to 5-hydromethylfurfural, SO4^2-/ZrO2-Al2O3 sped decarboxylation of 5-hydromethylfurfural to levulinic acid, and SO4^2-/ZrO2 superacids modified by doping metal ions sped both hydrolysis of glucose and decarboxylation of 5-hydromethylfurfural. |
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| Keywords: | SO4^2-／ZrO2 modify levulinic acid |
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