Synthesis and evaluation of the thermal properties of biosourced poly(ether)ureas and copoly(ether)ureas from 1,4:3,6‐dianhydrohexitols

A new series of poly(ether)ureas were prepared by solution polyaddition of three diamines based on 1,4:3,6‐dianhydrohexitols with three types of diisocyanate. The corresponding poly(ether)ureas were obtained with high yields. They were characterized by various analytical techniques (NMR, TGA and differential thermal analysis, DSC). NMR spectroscopy allowed us to confirm structure type and to optimize reaction conditions and DSC proved the high thermal properties of the products obtained (T_g and T_m in the range 126 ? 158 °C and 235 ? 330 °C respectively). Then, copoly(ether)ureas partially based on commercial diamines were synthesized in order to reduce polymer cost and tune their thermal behaviour. The reactivity of both diamines was evaluated by their incorporation in the polymer by means of NMR spectra. Then their thermal properties were compared with fully commercial diamine based polyureas by DSC studies. © 2014 Society of Chemical Industry