首页 | 本学科首页   官方微博 | 高级检索  
     

表面活性剂对水驱普通稠油油藏的乳化驱油机理
引用本文:孙宝泉,吴光焕,赵红雨,吴 伟,孙 超. 表面活性剂对水驱普通稠油油藏的乳化驱油机理[J]. 油田化学, 2024, 41(1): 138-145
作者姓名:孙宝泉  吴光焕  赵红雨  吴 伟  孙 超
作者单位:中国石化胜利油田分公司勘探开发研究院,山东 东营 257015;中国石化胜利油田分公司勘探开发研究院,山东 东营 257016;中国石化胜利油田分公司,山东 东营 257000;中国石化胜利油田分公司山东东胜精攻石油开发股份公司,山东 东营 257000
基金项目:国家自然科学基金“难采稠油多元热复合高效开发机理与关键技术基础研究”(项目编号U20B6003),中国石化课题“浅薄层超稠油多元热复合开发关键技术研究与应用”(项目编号P21037-4)
摘    要:为了研究乳化降黏驱油剂对不同渗透率的水驱普通稠油油藏的驱油效率和孔隙尺度增效机理,选取了烷基酚聚氧乙烯醚(J1)、α-烯基磺酸盐类表面活性剂(J2)、十二烷基羟磺基甜菜碱(J3)、J3与烷基酚聚氧乙烯醚羧酸盐复配表面活性剂(J4)作为驱油剂,开展了4种驱油剂一维驱油和微观驱油模拟实验,明确了乳化降黏驱油剂在孔隙尺度的致效机理。结果表明,降低界面张力对提高驱油效率的作用大于提高乳化降黏率。在油藏条件下,乳化降黏驱油剂需要依靠乳化降黏和降低界面张力的协同增效作用,才能大幅提高驱油效率。乳化降黏驱油剂的乳化能力越强、油水界面张力越低,驱油效率增幅越大。当化学剂乳化降黏率达到95%时,油水界面张力从10-1mN/m每降低1个数量级,化学剂在高渗透和低渗透岩心中的驱油效率依次提高约10.0%和7.8%。乳化降黏驱油剂注入初期通过降低界面张力,使得高渗透岩心和低渗透岩心中的驱替压力分别为水驱注入压力的1/2和1/3,从而提高注入能力。注入后期大块的原油被乳化形成大量不同尺寸的油滴,增强原油流动性,提高驱油效率。乳化形成的界面相对稳定的稠油油滴,能暂堵岩石的喉道和大块稠油与岩石...

关 键 词:普通稠油  驱油剂  水驱  乳化  降黏  界面张力  致效机理
收稿时间:2023-03-06
修稿时间:2022-05-31

Oil Emulsion and Displacement Mechanism of Surfactants during Water Flooding in Common Heavy Oil Reservoir
SUN Baoquan,WU Guanghuan,ZHAO Hongyu,WU Wei,SUN Chao. Oil Emulsion and Displacement Mechanism of Surfactants during Water Flooding in Common Heavy Oil Reservoir[J]. Oilfield Chemistry, 2024, 41(1): 138-145
Authors:SUN Baoquan  WU Guanghuan  ZHAO Hongyu  WU Wei  SUN Chao
Affiliation:Exploration and Development Research Institute,Shengli Oilfield Company,Sinopec,Dongying,Shandong 257015,P R of China;Exploration and Development Research Institute,Shengli Oilfield Company,Sinopec,Dongying,Shandong 257016,P R of China;Shengli Oilfield Company,Sinopec,Dongying,Shandong 257000,P R of China;Dongsheng Jinggong Petroleum Development Corporation,Shengli Oilfield Company,Sinopec,Dongying,Shandong 257000,P R of China
Abstract:Alkylphenolpolyethoxylate(J1),α-alkenyl sulfonate surfactant(J2),dodecyl hydroxysulfobetaine(J3)and combinational surfactants(J4)were selected as oil displacing agents,in order to study the oil displacement efficiency and pore scale enhancement mechanism of emulsification viscosity reducing oil displacing agents in water flooding for common heavy oil reservoirs with different permeability. The simulation experiments of one-dimensional displacement and micro-displacement of 4 kinds of displacement agents were carried out. The mechanism of emulsifying viscosive-reducing oil displacement agent at pore scale was clarified. The results showed that reducing interfacial tension had more effect on improving oil displacement efficiency than increasing emulsification viscosity reduction. Emulsified viscosity reducing oil displacement agents relied on the synergistic effect of emulsified viscosity reducing and interfacial tension reduction,in order to significantly improve oil displacement efficiency in reservoir. The stronger the emulsification ability and lower the interfacial tension between oil and water of emulsified viscosity reducing oil displacement agents,the greater the increase in oil displacement efficiency was. When the viscosity reduction rate of chemical emulsification reached 95%,the interfacial tension between oil and water decreased by one order of magnitude from 10-1 mN/m,the oil displacement efficiency of chemical agents in high permeability and low permeability cores increased about 10.0%and 7.8% respectively. At the initial stage of oil displacement agent injection,the displacement pressure of high permeability and low permeability core was 1/2 and 1/3 of the water flooding pressure by reducing the interfacial tension respectively,so as to improve the injection capacity. At the later stage of injection,large blocks of crude oil were emulsified to form a large number of oil droplets with different sizes,which enhanced the fluidity of crude oil and improved the efficiency of oil displacement. The viscous oil droplets formed by emulsification with relatively stable interface could temporarily block the throat of rock and the channel formed by large heavy oil and rock particles. Through the temporary plugging superposition effect,the displacement pressure in high permeability and low permeability core was 5.2 times and 32.3 times as high as that of water flooding respectively,so the injection pressure was greatly increased and then the plane sweep area was expanded. Viscosity reducing oil displacing agent could improve oil displacement efficiency and expand the sweep range at the same time. The research results pointed out the direction of research and development of water flooding agent for heavy oil,and laid a foundation for greatly improving the recovery of water flooding for common heavy oil.
Keywords:common heavy oil;oil-displacing agent;water flooding;emulsify;viscosity reduction;interfacial tension;mechanism of action
点击此处可从《油田化学》浏览原始摘要信息
点击此处可从《油田化学》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号