Selective isopentane formation from CH3OH on a new one-atomic layer ZrO2/ZSM-5 hybrid catalyst |
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| Authors: | Kiyotaka Asakura Mutsuto Aoki Yasuhiro Iwasawa |
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| Affiliation: | (1) Department of Chemistry, Faculty of Science, the University of Tokyo, Hongo, Bunkyo-ku, 113 Tokyo, Japan;(2) Department of Chemistry, Faculty of Science, Tokyo Science University, Kagurazaka, Shinjuku-ku, 162 Tokyo, Japan |
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| Abstract: | A new one-atomic layer ZrO2/ZSM-5 hybrid catalyst was prepared by using the repeated reactions between Zr(OC2H5)4 and of the OH groups of the external surfaces of ZSM-5, followed by calcination. The one-atomic layer ZrO2 attached on the ZSM-5 surface was characterized by means of X-ray diffraction, X-ray fluorescence and EXAFS. The ZrO2 overlayer is suggested to epitaxially grow on the ZSM-5(001) plane in a 111] direction of tetragonal ZrO2. The one-atomic layer ZrO2/ZSM-5 is a unique catalyst which produces selectively isopentane from CH3OH. |
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