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超声空化处理对高聚物粘结炸药表面结构的影响研究
引用本文:李敬明,田勇,邓志国,韦兴文.超声空化处理对高聚物粘结炸药表面结构的影响研究[J].含能材料,2006,14(1):35-37.
作者姓名:李敬明  田勇  邓志国  韦兴文
作者单位:中国工程物理研究院化工材料研究所,四川,绵阳,621900
基金项目:中国工程物理研究院基金资助(20030105)
摘    要:对以TATB为基的高聚物粘结炸药(JB1)进行了超声空化处理,并利用扫描电镜(SEM)观察了处理前后JB1炸药表面的细观形貌,用X射线能谱仪(EDS)检测了处理前后JB1炸药表面的相对元素含量。结果表明:超声空化处理可以使JB1炸药表面的粘结剂和炸药晶体的界面脱粘,使炸药晶体裸露。随着超声空化处理时间的延长,炸药晶体裸露程度加大,炸药晶体表面的小孔洞增加,表面也变得更加粗糙和疏松,起爆感度提高。

关 键 词:物理化学  超声空化处理  炸药  扫描电镜  X射线能谱
文章编号:1006-9941(2006)01-0035-03
收稿时间:2005-03-22
修稿时间:2005-06-02

Effect of Ultrasonic Cavitation Treatment on the Surface Structure of Polymer Bonded Explosive
LI Jing-ming,TIAN Yong,DENG Zhi-guo and WEI Xing-wen.Effect of Ultrasonic Cavitation Treatment on the Surface Structure of Polymer Bonded Explosive[J].Chinese Journal of Energetic Materials,2006,14(1):35-37.
Authors:LI Jing-ming  TIAN Yong  DENG Zhi-guo and WEI Xing-wen
Affiliation:Institute of Chemical Materials, CAEP, Mianyang 621900, China
Abstract:Ultrasonic cavitation treatment of polymer bonded explosive (JB-1) was undertaken. Before and after treatment,the surface structure of JB-1 explosive was observed by scanning electron microscope (SEM),and its element concentration was analyzed by X-ray energy spectrum (EDS). The results show that the interface between explosive crystal and binder is debonding during the ultrasonic treatment,and explosive crystals appear on the surface. With the treatment time increasing, the exposed extent of!explosive crystal and the number of micro-hole on the surface of explosive crystal increase. As the surface of JB-1 explosive become rough and loose after ultrasonic cavitation treatment,its initiation sensitivity may also increase.
Keywords:physical chemistry  ultrasonic cavitation treatment  explosive  SEM  EDS
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