Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution |
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| Authors: | MA Zheng;DONG Xiaoxia;Hu Yufeng;ZHANG Bosong;XU Changying;LIU Yansheng |
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| Affiliation: | 1.Shandong Province Key laboratory of Plant Nutrition and Fertilizer, Agriculture Resources and Environment Institute, Shandong Academy of Agricultural Science, Jinan 250100, China;2.State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China |
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| Abstract: | It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions. |
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| Keywords: | ionic liquid activity coefficients at infinite dilution organic reactions |
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