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电沉积Ni-20%Fe(质量)磁性合金箔工艺的研究
引用本文:刘天成,卢志超,李德仁,卢燕平,孙克,周少雄.电沉积Ni-20%Fe(质量)磁性合金箔工艺的研究[J].金属功能材料,2007,14(4):1-5.
作者姓名:刘天成  卢志超  李德仁  卢燕平  孙克  周少雄
作者单位:[1]钢铁研究总院,安泰科技股份有限公司,北京100081 [2]北京科技大学,材料科学与工程学院,北京100083
基金项目:国家高技术研究发展计划(863计划)资助项目(2003AA30251);北京市科技计划资助项目(D0405003040121)
摘    要:在硫酸盐-氯化物溶液体系中采用电沉积法制得了光亮Ni-Fe软磁合金箔,研究了n(Ni^2+)/n(Fe^2+)摩尔比,电流密度,镀液pH,镀液温度对电沉积Ni-Fe合金箔的铁含量的影响规律,确定了最佳工艺条件.验证性实验结果表明,在最佳工艺条件下制备的Ni-Fe合金箔是纳米晶合金,其Ni,Fe含量分别为80.4%(质量)和19.6%(质量).这种合金箔外观平整、致密,具有明显的层状结构,其饱和磁通密度(Ms)为94.23emu/g,剩余磁通密度(Mr)为4.33emu/g,矫顽力(Hc)为5.08Oe.

关 键 词:合金电镀  Ni-Fe软磁合金  
文章编号:1005-8192(2007)04-0001-05
修稿时间:2007-01-05

Investigation on Electroplating Conditions of Ni-20wt%Fe Magnetic Alloy Foil
LIU Tian-cheng, LU Zhi-chao , LI De-ren, LU Yan-ping, SUN Ke, ZHOU Shao-xiong.Investigation on Electroplating Conditions of Ni-20wt%Fe Magnetic Alloy Foil[J].Metallic Functional Materials,2007,14(4):1-5.
Authors:LIU Tian-cheng  LU Zhi-chao  LI De-ren  LU Yan-ping  SUN Ke  ZHOU Shao-xiong
Abstract:Bright Ni-Fe soft-magnetic alloy foil was prepared from sulphate-chloride bath solution by electroplating.The influence of n(Ni2+)/n(Fe2+) mole ratio,current density,pH and bath temperature on the content of Fe in the electrodeposited Ni-Fe alloy foil were investigated,and finally optimization technical conditions was found.Repeated experiment results shows that the Ni-Fe alloy foil plated with optimization conditions has nano-structure,chemical composition of the deposit is consisted of Ni 80.4wt% and Fe 19.6wt%.The alloy foil was fine,uniform and obvious layer structure.The saturation flux density(Ms),residual flux density(Mr) and coercivity(Hc) for the electroplated Ni-20wt%Fe alloy samples were respectively 94.23emu/g,4.33emu/g and 5.08Oe.
Keywords:alloy electrodeposition  Ni-Fe soft-magnetic alloy  foil
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