Kinetics of the SCN/(SCN)2 couple on platinum in acetonitrile |
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| Authors: | R PereiroAJ Arvía AJ Calandra |
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| Affiliation: | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas, División Electroquímica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina |
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| Abstract: | The electrode kinetics of the SCN−/(SCN)2 system has been studied on platinum in the temperature range from −12 to −3°C at different ammonium thiocyanate concentrations in acetonitrile in the presence of 0·1 M (C2H5)4N]ClO4. Quasi-steady E/I curves with a Pt rotating disk electrode and E/I curves at different linear potential-sweep rates were recorded under different experimental conditions. |
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