| 3,6-二肼基-1,2,4,5-四嗪及其盐的合成与表征 |
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| 引用本文： | 潘劼,何金选,陶永杰. 3,6-二肼基-1,2,4,5-四嗪及其盐的合成与表征[J]. 含能材料, 2006, 14(2): 116-117 |
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| 作者姓名： | 潘劼 何金选 陶永杰 |
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| 作者单位： | 中国航天科技集团公司四院四十二所,湖北,襄樊,441003;中国航天科技集团公司四院四十二所,湖北,襄樊,441003;中国航天科技集团公司四院四十二所,湖北,襄樊,441003 |
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| 摘 要： | 以三氨基胍盐酸盐和2,4-戊二酮为原材料,通过成环反应,氧化脱氢,肼基取代,三步合成了3,6-二肼基-1,2,4,5-四嗪,同时,对3,6-二肼基-1,2,4,5-四嗪的含能盐的合成进行了研究。对文献报道的反应路线进行了适当的放大研究。通过红外光谱分析、元素分析、质谱分析和1HNMR等方法对产物的结构特征进行了鉴定。
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| 关 键 词： | 有机化学 3 6-二肼基-1 2 4 5-四嗪 合成 四嗪 高氮化合物 |
| 文章编号： | 1006-9941（2006）02-0116-02 |
| 收稿时间： | 2005-07-26 |
| 修稿时间： | 2005-07-262005-11-17 |
Synthesis and Characterization of 3,6-Dihydrazine-1,2,4,5-tetrazine and its Energetic Salts |
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| PAN Jie,HE Jin-xuan and TAO Yong-jie. Synthesis and Characterization of 3,6-Dihydrazine-1,2,4,5-tetrazine and its Energetic Salts[J]. Chinese Journal of Energetic Materials, 2006, 14(2): 116-117 |
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| Authors: | PAN Jie HE Jin-xuan TAO Yong-jie |
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| Affiliation: | The 42nd Institute of the Fourth Academy of CASC, Xiangfan 441003, China |
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| Abstract: | 3,6-Dihydrazine-1,2,4,5-tetrazine and its energetic salts were synthesized from the easily available starting materials like triaminoguanidine and 2,4penatanedione.The synthesis route in literature was magnified properly.Moreover,the synthesized(compounds)were characterized by spectra analysis(IR,NMR,EA and MS) and the explosive properties(impact and friction sensitivity) and thermal properties(TGA/DTG) were studied. |
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| Keywords: | organic chemistry 3 6-dihydrazine-1 2 4 5-tetrazine synthesis tetrazine high-nitrogen energetic material |
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