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N、Ni共掺杂TiO2光催化剂的制备及对亚甲基紫降解性能研究
引用本文:马威,高航,张艳惠,李松田.N、Ni共掺杂TiO2光催化剂的制备及对亚甲基紫降解性能研究[J].应用化工,2012(9):1560-1562,1566.
作者姓名:马威  高航  张艳惠  李松田
作者单位:平顶山学院化学化工学院;河南大学化学化工学院
基金项目:河南省科技计划重点项目(102102310298)
摘    要:以硫脲、硝酸镍、钛酸四丁酯为原料,用溶胶-凝胶法制备了纯TiO2和不同比例N、Ni掺杂的TiO2的光催化剂样品,用紫外-可见分光光度计进行了表征。结果表明,经过掺杂的TiO2光催化剂的吸收边向可见光方向移动,TiO2可见光催化活性提高,掺杂量为0.15 g,pH=9,温度为30℃时,对亚甲基紫的脱色效果最好。

关 键 词:溶胶-凝胶  掺杂TiO2  光催化  吸光度

Research on N,Ni TiO2 light of the preparation of catalysts doped and the methyl violet degradation performance
MA Wei,GAO Hang,ZHANG Yan-hui,LI Song-tian.Research on N,Ni TiO2 light of the preparation of catalysts doped and the methyl violet degradation performance[J].Applied chemical industry,2012(9):1560-1562,1566.
Authors:MA Wei  GAO Hang  ZHANG Yan-hui  LI Song-tian
Affiliation:1(1.School of Chemistry and Chemical Engineering,Pingdingshan University,Pingdingshan 467000,China; 2.School of Chemistry and Chemical Engineering,Henan University,Kaifeng 475000,China)
Abstract:With thiourea,nitric acid nickel,tetra butyl titanate ester as raw material and using sol-gel process with different proportion of pure TiO2 and N,Ni TiO2 light catalysts doped samples.By UV-Vis spectra photometry instrument was characterized.Results showed that after doped the absorption of TiO2 light catalyst to visible direction,edge of TiO2 visible catalytic activity improved,doping quantity 0.15 g,pH=9 and for 30 ℃ the methyl violet decoloration rate the best effect.
Keywords:sol-gel  doping TiO2  photocatalytic  absorbency
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