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苯与十二烯烷基化悬浮床催化精馏塔的模拟
引用本文:王健,王二强,陈标华,李成岳.苯与十二烯烷基化悬浮床催化精馏塔的模拟[J].化工学报,2005,56(9):1654-1659.
作者姓名:王健  王二强  陈标华  李成岳
作者单位:北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029;北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029;北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029;北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029
基金项目:国家重点基础研究发展规划项目(G2000048006).
摘    要:建立了苯与十二烯烷基化悬浮床催化精馏过程的动态平衡级模型,模型对过渡过程达到定态时的系统性能预测与定态实验数据和定态模拟结果吻合良好.利用模型模拟,就苯的进料位置、苯和混合烃进料流量的正向扰动对系统性能的影响进行了研究.结果表明:在给定条件下系统仅存在一个定态;反应段最后一块塔板是苯的最优进料位置;系统对于所施加量级的扰动是稳定的,其抗干扰能力很强.

关 键 词:悬浮床催化精馏  数学模型  定态模拟  动态模拟
文章编号:0438-1157(2005)09-1654-06
收稿时间:09 13 2004 12:00AM
修稿时间:2004-09-132004-12-02

Simulation of suspension catalytic distillation column for alkylation of benzene with C12 olefins
WANG Jian,WANG Erqiang,CHEN Biaohua,LI Chengyue.Simulation of suspension catalytic distillation column for alkylation of benzene with C12 olefins[J].Journal of Chemical Industry and Engineering(China),2005,56(9):1654-1659.
Authors:WANG Jian  WANG Erqiang  CHEN Biaohua  LI Chengyue
Affiliation:The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
Abstract:A dynamic equilibrium stage model of the suspension catalytic distillation process for alkylation of benzene with C12 olefins is developed. The prediction for steady-state based on the proposed mathematical model agrees with the steady-state experimental data and simulation results well. The stationary and dynamic models developed are used to simulate the influence of the location of benzene feed stream, disturbances of benzene and mixed hydrocarbon feed flow rates upon the suspension catalytic distillation system. Only one steady-state can exist in the system for the given conditions, and the last stage in reaction section is the optimal location of benzene feed stream. The system is stable for the imposed disturbances, and its anti-disturbance ability is very strong.
Keywords:suspension catalytic distillation  mathematical model  stationary simulation  dynamic simulation
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