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Surface Diffusivity under High-Pressure Gas
Authors:Makoto Nanko  Kozo Ishizaki  Takao Fujikawa  Yoshihito Kondo
Affiliation:Department of Materials Science and Engineering, School of Mechanical Engineering, Nagaoka Gijutsu-Kagaku Daigaku (Nagaoka University of Technology), Nagaoka, Niigata 940–21, Japan;Kobe Steel Ltd, Co., Takasago, Hyogo 676, Japan;Kagawa Industrial Technology Center, Takamatsu, Kagawa 761, Japan
Abstract:The sintering behavior of TiO2 under high-pressure gas (100 MPa) was studied with respect to densification rate, decreasing rate of specific surface area, and narrowing rate of pore size distribution. At the low sintering temperature (800°C) used in this study, the densification rate under high- pressure gas was similar to that under low (i.e., 1 atm) pressure. The specific surface area decreased and the pore size distribution narrowed at a faster rate under high- pressure gas than under low-pressure gas. These results imply that high-pressure gas enhances surface diffusion.
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