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纳米石墨片/环氧树脂复合材料的制备及性能
引用本文:陈星运,贺江平,舒远杰. 纳米石墨片/环氧树脂复合材料的制备及性能[J]. 化工进展, 2011, 30(6): 1306-1312
作者姓名:陈星运  贺江平  舒远杰
作者单位:1.西南科技大学材料科学与工程学院,四川 绵阳 621010;2中国工程物理研究院化工材料研究所,四川 绵阳 621900
基金项目:中国工程物理研究院科学技术发展基金,中物院化工材料研究所新材料中心项目
摘    要:分别采用低温固化剂和高温固化剂制备了纳米石墨片/环氧树脂复合材料。通过电阻测试仪和材料试验机研究了纳米石墨片的含量对复合材料导电性能和力学性能的影响规律,并将溶液混合法与直接混合法制备的复合材料的性能进行对比,同时比较了纳米复合材料的性能与微粉石墨/环氧树脂复合材料的性能。结果表明,溶液混合法制备的复合材料逾渗阈值更低,可得到填料质量分数达60%、体积电阻率为0.0085 Ω·cm的纳米复合材料。当填料质量分数高于4%时,纳米复合材料的力学性能低于微粉复合材料。

关 键 词:纳米石墨片  环氧树脂  溶液混合法  导电性能  力学性能

Preparation and properties of graphite nanosheets/epoxy composites
CHEN Xingyun,HE Jiangping,SHU Yuanjie. Preparation and properties of graphite nanosheets/epoxy composites[J]. Chemical Industry and Engineering Progress, 2011, 30(6): 1306-1312
Authors:CHEN Xingyun  HE Jiangping  SHU Yuanjie
Affiliation:1Institute of Material Science and Engineer,Southwest Science and Technology University,Mianyang 621010,Sichuan,China;2Institute of Chemical Materials,China Academy of Engineering Physics,Mianyang 621900,Sichuan,China
Abstract:Graphite nanosheets/epoxy composites were prepared by the low curing mode and high temperature curing mode,respectively. The influence of the content of graphite nanosheets on the conductive properties and mechanical properties of composites were studied with the resistance testing and materials testing machines. The properties of composites prepared by the solution mixing method and directly mixing method were compared with each other,and the properties of nano-composites were compared with micro-powder composites. It was shown that the composites prepared by the solution mixing method could have lower percolation threshold. When the content of graphite nanosheets reached 60%,the volume resistivity was 0.0085 Ω·cm. The mechanical properties of nano-composites were inferior to the micro-powder composites with the filler content higher than 4.0%.
Keywords:
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