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偏氯乙烯聚合物基多孔炭的制备及应用研究进展
引用本文:吴启强,雷衍庆,包永忠. 偏氯乙烯聚合物基多孔炭的制备及应用研究进展[J]. 化工生产与技术, 2011, 18(3): 45-49,71. DOI: 10.3969/j.issn.1006-6829.2011.03.014
作者姓名:吴启强  雷衍庆  包永忠
作者单位:1. 浙江大学化学工程与生物工程学系,化学工程联合国家重点实验室,杭州310027
2. 陕西秦牛集团公司,陕西渭南,714000
摘    要:叙述了以偏氯乙烯聚合物为碳源,通过高温直接炭化制备微孔为主的多孔炭,及炭化、催化活化和模板法制备中孔-微孔复合多孔炭的研究进展,归纳了影响2种新型多孔炭制备过程中炭材料孔隙的主要因素.介绍了偏氯乙烯聚合物基微孔和中孔-微孔复合多孔炭材料在超级电容器电极、催化剂负载和吸附分离等方面的应用.认为偏氯乙烯聚合物基多孔炭属新型...

关 键 词:偏氯乙烯聚合物  炭化  多孔炭

Research Development on Preparation and Application of Porous Carbons from Vinylidene Chloride Polymers
Wu Qiqiang,Lei Yanqing,Bao Yongzhong. Research Development on Preparation and Application of Porous Carbons from Vinylidene Chloride Polymers[J]. Chemical Production and Technology, 2011, 18(3): 45-49,71. DOI: 10.3969/j.issn.1006-6829.2011.03.014
Authors:Wu Qiqiang  Lei Yanqing  Bao Yongzhong
Affiliation:1(1.State Key Laboratory of Chemical Engineering,Department of Chemical and Biological Engineering,Zhejiang University,Hangzhou,310027;2.Shanxi Qinniu Group Co.,Weinan,Shanxi 714000)
Abstract:The research development on the preparation of microporous and meso-micro composite porous carbons from vinylidene chloride(VDC) polymers were reviewed in this paper.Using VDC polymers as the carbon source,microporous carbons can be prepared by a direct carbonization process and meso-micro composite porous carbons can be prepared by a carbonization/activation process or templating methods.The main factors affecting the pore structures of the obtained carbons were introduced.The application of the new porous carbons on electrical double layer capacitors,supporting of catalyst and adsorption/separation,were also reviewed.It is considered that VDC polymer-based carbons exhibit excellent properties,and their preparation and application technologies should be further investigated.
Keywords:vinylidene chloride polymer  carbonization  porous carb
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