Abstract: | In the study, polyaniline/reduced‐graphene oxide (PANI‐RGO) composites, fabricated by loading 2, 5, and 8wt% graphene oxide, was prepared by in‐situ emulsion polymerization and reduction. They are characterized by Fourier transform infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy. Epoxy coatings adding PANI and PANI‐RGO composites were coated on the surface of AA5083 Al alloy. The anticorrosion performance of the coatings is measured by electrochemical impedance spectroscopy and potentiodynamic polarization curve in 3.5wt% NaCl solution. The results demonstrate that the epoxy/PANI‐RGO coating exhibits a better protection against AA5083 alloy corrosion compared with the epoxy/PANI coating. Enhancement of the passivation performance of PANI was obtained by the addition of RGO into epoxy/PANI coating system. |