Electrochemical Fabrication of Porous Au Film on Ni Foam for Nitrogen Reduction to Ammonia

Electrochemical reduction of N₂ to NH₃ provides an alternative strategy to replace the industrial Haber–Bosch process for facile and sustainable production of NH₃. The development of efficient electrocatalysts for the nitrogen reduction reaction (NRR) is highly desired. Herein, a micelle‐assisted electrodeposition method is presented for the direct fabrication of porous Au film on Ni foam (pAu/NF). Benefiting from its interconnected porous architectonics, the pAu/NF exhibits superior NRR performance with a high NH₃ yield rate of 9.42 µg h^?1 cm^?2 and a superior Faradaic efficiency of 13.36% at ?0.2 V versus reversible hydrogen electrode under the neutral electrolyte (0.1 m Na₂SO₄). The proposed micelle‐assisted electrodeposition strategy is highly valuable for future design of active NRR catalysts with desired compositions toward various electrocatalysis fields.