| 纺织品中小分子醛的液相色谱串联质谱法测定 |
| |
| 引用本文： | 金美菊,钱微君,翟震宇,刘优娜. 纺织品中小分子醛的液相色谱串联质谱法测定[J]. 印染, 2021, 0(1): 65-69 |
| |
| 作者姓名： | 金美菊 钱微君 翟震宇 刘优娜 |
| |
| 作者单位： | 宁波市产品食品质量检验研究院（宁波市纤维检验所） |
| |
| 摘 要： | 建立了纺织品中微量甲醛、乙醛、丙醛、丁醛和戊醛的高效液相色谱串联质谱测定方法.以2.0％磷酸为溶剂,以超声波辅助技术进行萃取,采用2,4-二硝基苯肼(DNPH)衍生,衍生物在BEH C18色谱柱(75 mm×2.0 mm,2.2μm)上以甲醇-0.05％甲酸为流动相,采用梯度洗脱分离,电喷雾电离(ESI)正离子多反应监...
|
| 关 键 词： | 测试 液相色谱串联质谱法 衍生化 小分子醛 2,4-二硝基苯肼 纺织品 |
Determination of low molecular mass aldehydes in textiles by LC-MS method |
| |
| JIN Meiju,QIAN Weijun,ZHAI Zhenyu,LIU Youna. Determination of low molecular mass aldehydes in textiles by LC-MS method[J]. Dyeing and Finishing, 2021, 0(1): 65-69 |
| |
| Authors: | JIN Meiju QIAN Weijun ZHAI Zhenyu LIU Youna |
| |
| Affiliation: | (Ningbo Academy of Product and Food Quality Inspection(Ningbo Fibre Inspection Institute),Ningbo 315048,China) |
| |
| Abstract: | A high performance liquid chromatography tandem mass spectrometry(LC-MS/MS)method for the determination of trace formaldehyde,acetaldehyde,propionaldehyde,butyraldehyde and valeral?dehyde in textiles is established.The samples are extracted with 2.0%phosphate by ultrasonic assistive technology,and then the analytes are derivated by DNPH.The derivatives are separated on a BEH C18 column(75 mm×2.0 mm,2.2μm)by using 0.05%formic acid/methanol solution as the mobile phase with the gradient elution.Quantitative detection is performed in positive multi-reaction monitoring(MRM)mode by using external standard method.The five aldehydes have good linearity in the range of 2.0~200.0μg/L(calculated by aldehyde),the correlation coefficient R 2>0.9990,the recovery rates of the method are 89.0%~98.5%at the three spiked levels,and the relative standard deviations(RSDs)are 2.3%~7.4%. |
| |
| Keywords: | testing liquid chromatography tandem mass spectrometry derivation low molecular mass aldehyde DNPH textile |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
