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酯型阳离子染料易染共聚酯纤维的研究──Ⅲ、共聚酯流变性能的研究
引用本文:魏高富,钟伟宏.酯型阳离子染料易染共聚酯纤维的研究──Ⅲ、共聚酯流变性能的研究[J].合成技术及应用,1996,11(3):8-13.
作者姓名:魏高富  钟伟宏
作者单位:江苏仪征化纤股份有限公司产品技术开发中心
摘    要:使用Instron3211型和BrabenderPLD331型毛细管流交仪研究了酯型ECDP的流变性能。结果表明:酯型ECDP具有剪切变稀特性,随着第四组分含量的增加.共聚酯熔体的非牛顿指数n增大,表观粘度ηa、粘流活化能(ΔEηa)rw和结构粘度指数Δη下降,流动性能得到改善,对可纺性有利。

关 键 词:表观粘度,结构粘度,流变性能,酯型ECDP

STUDY ON THE ESTER-TYPE ECDP Ⅲ. RHEOLOGICAL PROPERTIES OF THE COPOLYSTERS
Wei Gaofu,Zhong Weihong and Sun Bingsheng.STUDY ON THE ESTER-TYPE ECDP Ⅲ. RHEOLOGICAL PROPERTIES OF THE COPOLYSTERS[J].Synthetic Technology and Application,1996,11(3):8-13.
Authors:Wei Gaofu  Zhong Weihong and Sun Bingsheng
Affiliation:Research Institute of Yizheng Chemical Fibre Co. Ltd
Abstract:Rheological properties of ester-type ECDP were studied by means of an InstronCapillary Rheometer Model 3211 and a Brabender Capill ary Rheometer Model PLD 331.The results showed that the copolyesters have the property of shear thinning;with increasingcontents of the fourth component, the non-Newton Index n of the copolyester melts willincrease, while the values of apparent viscosity ηa, flow - activation energy (ΔEηa) γw andstructural vicosity index Δη will decrease, which is beneficial to the spinnability of thecopolyesters.
Keywords:apparent vicosity  structural vicosity  rheological property  ECDPfibers  
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