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Froth stability and entrainment evaluation of a novel frother for KCl/NaCl flotation
Authors:Linjian Wang  Yanxia Xu  Xingfu Song
Affiliation:1. Engineering Research Center of Resources Process Engineering, Ministry of Education Resource, East China University of Science and Technology, Shanghai, People's Republic of China

National Engineering Research Center for Integrated Utilization of Salt Lake Resource, East China University of Science and Technology, Shanghai, People's Republic of China

Contribution: Data curation (lead), ?Investigation (lead), Methodology (lead), Visualization (lead), Writing - original draft (lead);2. State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai, People's Republic of China;3. Engineering Research Center of Resources Process Engineering, Ministry of Education Resource, East China University of Science and Technology, Shanghai, People's Republic of China

Abstract:The rate of KCl recovery by froth flotation using low-grade carnallite is 70%–85%. Herein, a novel frother, dipropylene glycol butyl ether (DPNB), was prepared to increase the flotation efficiency of KCl recovery systems. DPNB could be applied at only half the dosage of the conventional frother methyl isobutyl carbinol (MIBC) and achieve a KCl recovery rate of 94.8%–98.6% with a high KCl grade (63.2%–66.5%). To date, these results are the best reported for pneumatic flotation. DPNB had a 10% higher maximum dynamic stability factor compared with MIBC; moreover, the apparent entrainment velocity of DPNB was half that of MIBC. The molecular structure of DPNB had hydroxyl and ether groups, which promoted interactions with water, thereby contributing to its excellent froth stability. DPNB is environment friendly owing to its low volatility and, thus, a promising frother for the green and highly efficient flotation of KCl/NaCl.
Keywords:dipropylene glycol butyl ether  flotation technology  froth properties  froth stabilizing mechanism  KCl/NaCl flotation
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