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Effect of Surface Treatment on the Selective Photocatalytic Oxidation of Benzyl Alcohol into Benzaldehyde by O2 on TiO2 Under Visible Light
Authors:Shinya Higashimoto  Kohei Okada  Tomoki Morisugi  Masashi Azuma  Hiroyoshi Ohue  Tae-Ho Kim  Masaya Matsuoka  Masakazu Anpo
Affiliation:1. Department of Applied Chemistry, College of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka, 535-8585, Japan
2. Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan
Abstract:The photocatalytic oxidation of benzyl alcohol into benzaldehyde proceeded with high conversion and selectivity on a TiO2 photocatalyst by O2 under visible light irradiation. Surface complex formed by the interaction of benzyl alcohol with the Ti sites and/or surface OH groups of TiO2 play an important role in the absorption of visible light and unique selective photocatalytic reaction.
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