| 配体二-(2-吡啶基)苯基膦的合成及表征 |
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| 引用本文： | 薛丁江,韩志旺. 配体二-(2-吡啶基)苯基膦的合成及表征[J]. 应用化工, 2009, 28(2) |
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| 作者姓名： | 薛丁江 韩志旺 |
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| 作者单位： | 太原科技大学,材料科学与工程学院,山西,太原,030024 |
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| 摘 要： | 通过强碱性亲核试剂PhP2-与2-氯吡啶反应合成了配体二-(2-吡啶基)苯基膦(PhPPy2),用核磁共振氢谱对该膦配体的结构进行了表征。本合成方法使配体PhPPy2的合成产率提高到83%,且副反应少,合成的产物易分离。
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| 关 键 词： | 配体 二-(2-吡啶基)苯基膦 合成 |
Synthesis and characterization of bis(2-pyridyl)phenylphosphine |
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| XUE Ding-jiang,HAN Zhi-wang. Synthesis and characterization of bis(2-pyridyl)phenylphosphine[J]. Applied chemical industry, 2009, 28(2) |
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| Authors: | XUE Ding-jiang HAN Zhi-wang |
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| Abstract: | The ligand bis(2-pyridyl)phenylphosphine(PhPPy2) was synthesized by the reaction of strong alkaline nucleophiles PhP2-and 2-chloropyridine.The structure of this phosphine ligand was characterized by nuclear magnetic resonance spectroscopy.Through this synthetic method,the yield of PhPPy2 was up to 83%,with fewer side effects.The synthetic product was easy to separate at the same time. |
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| Keywords: | ligand bis(2-pyridyl)phenylphosphine synthesis |
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