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Synthesis,Characterization and Surface Activities of Cationic Polysaccharide (Aloe) Schiff Base Surfactants
Authors:Mohamad F Zaky  Abelfattah M Badawi  Ibrahim El Sabbah  Reda A Abdel Ghani  Mostafa E Hendawy
Affiliation:1. , Egyptian Petroleum Research Institute, Cairo, Egypt;2. , Al‐Azhar University, Cairo, Egypt
Abstract:Synthesis of cationic polysaccharide (Aloe) Schiff base surfactants was described and their chemical structures were confirmed by using FTIR spectroscopic, H‐NMR and UV analysis. The surface activities of these surfactants were measured, including surface tension, critical micelle concentration, effectiveness, efficiency, maximum surface excess and minimum surface area at 25 °C, interfacial tension and emulsification power at 25 °C. Adsorption and micellization free energies of these amphiphiles in their solutions showed a good tendency towards adsorption at the interfaces.
Keywords:Quaternary ammonium amphiphiles  Micellization  Adsorption  Surface properties polysaccharide  Schiff base
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