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Interfacial Rheology of Mixed Surfactants at the Oil/Water Interface
Authors:Jinyu Pang  Sujun Du  Runtian Chang  Qiang Pei  Dongxia Cui
Affiliation:1. Shanxi Transportation Research Institute, Taiyuan, People's Republic of China;2. Key Lab of Highway Construction and Maintenance Technology in Loess Region, Ministry of Transport, PRC, Taiyuan, People's Republic of China
Abstract:The interfacial rheology of surfactant mixtures (SBT and Tween® 80) at the oil/water interface is investigated using toluene as a model oil. The surfactant ratio in the mixed system has an important impact on the interfacial properties. After adding Tween® 80, the interfacial tension and modulus of SBT show remarkable changes. Compared with the individual SBT or Tween® 80 systems, the interfacial properties of the mixed surfactant system improve, especially at a 1:1 ratio. At the optimum ratio, synergistic adsorption takes place resulting in improved asphalt emulsion stability.
Keywords:Interfacial rheology  Surfactant  Oil/water interface  Emulsion stability
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