Increased Emulsion Stability for Reverse Y‐Shaped Sugar‐Based Surfactants |
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Authors: | Tammar Hussein Ali Hairul Anuar Bin Tajuddin Rusnah Syahila Duali Hussen Thorsten Heidelberg |
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Affiliation: | , Chemistry Department, Faculty of Science, University of Malaya, Kuala Lumpur, Malaysia |
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Abstract: | A series of reverse Y‐shaped surfactants containing aromatic and aliphatic linkers to combine two short hydrocarbon chains and one carbohydrate head group was prepared. Liquid crystalline behavior, air–water interfacial properties, and efficiency as an emulsifier was investigated for each reverse Y‐shaped surfactant. All reverse Y‐shaped surfactants mediated higher emulsion stabilities for water‐in‐oil compared to common typical reference surfactants, reflecting an improved ability to cope with a curvature towards water. The introduction of a benzene ring into the linker substantially increased the affinity of the surfactant for hydrophobic media, resulting in improved emulsion stability for both water‐in‐oil and oil‐in‐water. |
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Keywords: | Reverse Y‐shaped surfactant Sugar‐based surfactant Double alkyl chain Water‐in‐oil emulsion Click chemistry |
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