| 2,6-萘二羧酸改性双酚A环氧树脂的性能 |
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| 引用本文： | 夏海,孟军虎,王宏刚. 2,6-萘二羧酸改性双酚A环氧树脂的性能[J]. 工程塑料应用, 2016, 0(5): 15-18. DOI: 10.3969/j.issn.1001-3539.2016.05.004 |
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| 作者姓名： | 夏海 孟军虎 王宏刚 |
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| 作者单位： | 1. 中国科学院兰州化学物理研究所，固体润滑国家重点实验室，兰州 730000; 中国科学院大学，北京 100049;2. 中国科学院兰州化学物理研究所，固体润滑国家重点实验室，兰州 730000 |
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| 基金项目： | 中国科学院百人计划项目，甘肃省重大科技专项计划(1302GKDE008) |
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| 摘 要： | 用2,6-萘二羧酸(NDCA)对双酚A环氧树脂进行改性,研究了NDCA加入量对双酚A环氧树脂黏度、耐热性和力学性能的影响。结果表明,NDCA能提高环氧树脂的储能模量和玻璃化转变温度,玻璃化转变温度最高达到113℃。NDCA的质量分数小于0.5%时,改性环氧树脂的断裂伸长率随着NDCA加入量的增加逐渐提高,最高达12%。结合傅立叶变换红外光谱测试,提出了NDCA改性双酚A环氧树脂的机理,并对改性环氧树脂性能增强的机理进行了探讨。
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| 关 键 词： | 2,6-萘二羧酸 双酚A环氧树脂 耐热性 力学性能 动态热机械分析 |
Properties of Bisphenol A Epoxy Resin Modiifed by 2,6-Naphthalenedicarboxylic Acid |
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| Abstract: | Bisphenol A epoxy resin was modified by 2,6-naphthalenedicarboxylic acid (NDCA). The effects of the content of 2,6–naphthalenedicarboxylic acid on the viscosity,heat resistance and mechanical properties of modified resin were studied. As a result,the storage modulus and glass transition temperature of epoxy resin increase with increasing the content of NDCA, the maximum glass transition temperature of modified resin reaches 113℃. Elongation at break is improved when the content of NDCA is between 0–0.5 wt%. The modification mechanism was proposed based on the Fourier transform infrared spectrometer and the reason of performance improvement was analysed. |
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| Keywords: | 2,6-naphthalenedicarboxylic acid bisphenol A epoxy resin heat resistance mechanical property dynamic mechanical analysis |
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