| 钛硅分子筛TS-1合成及催化环己酮氨氧化的研究进展 |
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| 引用本文： | 梁新华,王亚权,王莅,张香文,米镇涛.钛硅分子筛TS-1合成及催化环己酮氨氧化的研究进展[J].现代化工,2003,23(4):10-13. |
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| 作者姓名： | 梁新华 王亚权 王莅 张香文 米镇涛 |
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| 作者单位： | 天津大学化工学院,天津,300072 |
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| 基金项目： | 国家重点基础研究发展计划项目 (G2 0 0 0 0 4 80 0 5 |
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| 摘 要： | 钛硅分子筛TS- 1催化的环己酮氨氧化反应是一个绿色过程。介绍了TS- 1分子筛的合成、TS- 1分子筛催化的环己酮氨氧化及环己酮氨氧化与过氧化氢生产的集成。指出提高催化剂的性能、降低其生产成本是今后研究的重点 ,绿色氧化剂过氧化氢的生产与氨氧化过程的集成是今后环己酮肟生产的发展方向
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| 关 键 词： | 钛硅分子筛TS-1 环己酮肟 氨氧化 集成过程 |
| 文章编号： | 0253-4320(2003)04-0010-04 |
| 修稿时间： | 2002年12月23 |
Advances in TS-1 molecular seive synthesis and ammoximation of cyclohexanone catalyzed by TS-1 |
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| LIANG Xin hua,WANG Ya quan,WANG Li,ZHANG Xiang wen,MI Zhen tao.Advances in TS-1 molecular seive synthesis and ammoximation of cyclohexanone catalyzed by TS-1[J].Modern Chemical Industry,2003,23(4):10-13. |
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| Authors: | LIANG Xin hua WANG Ya quan WANG Li ZHANG Xiang wen MI Zhen tao |
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| Abstract: | The ammoximation of cyclohexanone with H 2O 2 and ammonia catalyzed by titanium silicalite 1 (TS 1) is an environment friendly process.The research progress in TS 1 synthesis,ammoximation of cyclohexanone and the integrated process of cyclohexanone oxime production are introduced.It is indicated that improving the physical properties of the catalyst and reducing the cost of production are major work to be done,the integrated process of H 2O 2 production and ammoximation of cyclohexanone should be attached with great importance to green chemical industry. |
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| Keywords: | titanium silicalite 1 (TS 1) cyclohexanone oxime ammoximation integrated process |
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