| 交联淀粉微球对对硝基甲苯的吸附行为研究 |
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| 引用本文： | 陈诚,郭睿,马璐. 交联淀粉微球对对硝基甲苯的吸附行为研究[J]. 印染助剂, 2012, 29(3): 30-34 |
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| 作者姓名： | 陈诚 郭睿 马璐 |
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| 作者单位： | 教育部轻化工助剂化学与技术重点实验室;陕西科技大学化学与化工学院,陕西西安710021 |
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| 摘 要： | 以可溶性淀粉为原料,通过反相悬浮聚合的方法合成交联淀粉微球(CSM).研究了CSM对对硝基甲苯(PNT)的吸附行为,利用扫描电镜(SEM)、傅里叶红外光谱仪(FT-IR)、X射线衍射仪(XRD)对CSM及其吸附产物进行表征,并分析了其吸附动力学特性和热力学性质.结果表明:在研究范围内,CSM对PNT吸附100 min后达到平衡,且吸附行为同时符合Langmuir方程和Freundlich方程;在不同温度下,CSM吸附PNT的吸附自由能变(ΔG)、吸附焓变(ΔH)、吸附熵变(ΔS)均为负值,吸附是一个自发、放热过程;CSM主要通过物理吸附方式吸附PNT.
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| 关 键 词： | 交联淀粉微球 对硝基甲苯 动力学 热力学 吸附机理 |
Study on the adsorption behavior of crosslinked starch microspheres for p-nitrotoluene |
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| CHEN Cheng , GUO Rui , MA Lu. Study on the adsorption behavior of crosslinked starch microspheres for p-nitrotoluene[J]. Textile Auxiliaries, 2012, 29(3): 30-34 |
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| Authors: | CHEN Cheng GUO Rui MA Lu |
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| Affiliation: | (Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry,Ministry of Education,Institute of Chemistry and Chemical Engineering,College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology,Xi’an 710021,China) |
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| Abstract: | The crosslinked starch microspheres(CSM) were prepared by the inverse suspension polymerization with soluble starch as raw materials.The adsorption behavior of CSM for p-nitrotoluene(PNT) was investigated.The structures of CSM before and after adsorption were characterized by scanning electron microscope(SEM),FT-IR spectroscopy and X-ray diffraction(XRD),and the kinetics and thermodynamics characteristics were also analyzed.The results showed that within the scope of the study,the adsorption reached equilibrium after 100 min,and the adsorption behavior accorded with both Langmiur and Freundlich equation.The free energy change ?驻G,enthalpy change ?驻H,entropy change ?驻S for p-nitrotoluene adsorbed by CSM were all negative at different temperatures.The adsorption was a spontaneous and exothermic process.The CSM absorb PNT mainly by means of physical adsorption. |
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| Keywords: | crosslinked starch microspheres p-nitrotoluene kinetics thermodynamics adsorption mechanism |
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