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BiVO4/膨润土对活性蓝19的吸附动力学
引用本文:李南南,魏岳挺,何瑾馨.BiVO4/膨润土对活性蓝19的吸附动力学[J].印染助剂,2012,29(3):14-17.
作者姓名:李南南  魏岳挺  何瑾馨
作者单位:东华大学化学化工与生物工程学院,纺织面料技术教育部重点实验室,上海201620
摘    要:制备了BiVO4/膨润土,并用XRD、FE-SEM进行了表征.研究了BiVO4/膨润土对活性蓝19的吸附动力学.结果表明:Bi-VO4/膨润土对活性蓝19的吸附在30 min基本达到平衡.在染料初始质量浓度为15~45 mg/L、温度为298~318 K时,BiVO4/膨润土对活性蓝19的吸附动力学数据符合准二级动力学方程,表观吸附活化能为28.75 kJ/mol,说明此吸附由化学吸附和物理吸附共同控制.

关 键 词:BiVO4/膨润土  活性蓝19  吸附  吸附动力学

Adsorption kinetics of BiVO4/bentonite for Reactive Blue 19
LI Nan-nan , WEI Yue-ting , HE Jin-xin.Adsorption kinetics of BiVO4/bentonite for Reactive Blue 19[J].Textile Auxiliaries,2012,29(3):14-17.
Authors:LI Nan-nan  WEI Yue-ting  HE Jin-xin
Affiliation:(College of Chemistry,Chemical Engineering and Biotechnology,Donghua University,The Key Lab of Textile Science & Technology,Ministry of Education,Shanghai 201620,China)
Abstract:BiVO4 /bentonite was prepared and characterized by XRD,FE-SEM.The adsorption kinetics of BiVO4 /bentonite for Reactive Blue 19 was investigated.The results indicated that equilibrium between the dye and BiVO4 /bentonite in the solution was established within 30 min.The adsorption kinetics data fitted very well with the pseudo-second-order kinetic equation as the initial concentration was between 15~45 mg/L and the experimental temperature was 298~318 K.The apparent activation energy of the adorption was 28.75 kJ/mol,which meant that the adsorption process was controlled by chemical adsorption and physicial adsorption.
Keywords:BiVO4 /bentonite  Reactive Blue 19  adsorption  adsorption kinetics
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