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Ethylene oligomerization promoted by group 8 metal complexes containing 2-(2-pyridyl)quinoxaline ligands
Affiliation:1. Dx;2. Department of Laboratory Medicine and Pathology, University of Alberta, Canada;3. Synergy Medical Clinic, Sherwood Park, Canada
Abstract:NiII, CoII and FeII complexes of 2-(2-pyridyl)quinoxaline were synthesized and used in the ethylene oligomerization with methyl-aluminoxane (MAO) as cocatalyst. The nickel complex system mainly produced α-olefins with good activity, while the cobalt and iron complexes showed only marginal activity.
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