Breakthrough Analysis OF H 2 S removal on CU-V-MO,CU-V,and CU-MO mixed oxides |
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Authors: | Sena Yaşyerli Gülşen Dogu AR Irfan Timur Dogu |
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Affiliation: | 1. Department of Chemical Engineering , Gazi University , Maltepe, Ankara, Turkey;2. Department of Chemical Engineering , Middle East Technical University , Ankara, Turkey |
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Abstract: | Kinetic studies carried out for the sorption of H 2 S in the presence and absence of hydrogen on Cu-V-Mo, Cu-V, and Cu-Mo mixed oxides gave detailed information about the reaction sequences. Formation of SO 2 even in the presence of hydrogen at the initial stages of the sorption process showed the partial reduction of the metal oxides prior to the sulfidation step. A sorption experiment carried out with Cu-Mo mixed oxide gave incomplete sulfidation of molybdenum, whereas with Cu-V mixed oxide complete sulfidation was obtained. Predictions of the breakthrough curves by the deactivation model showed good agreement with the experimental results. |
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Keywords: | H 2 S Sorption Breakthrough Analysis Deactivation Model Copper-based Oxide Sorbents |
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