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THE KRAMERS CHAIN MODEL FOR POLYMERS
Authors:R BYRON BIRD
Affiliation:Chemical Engineering Department and Rheology Research Center , University of Wisconsin , Madison, WI, 53706
Abstract:The freely jointed bead-rod chain (the “Kramers chain”) is a fairly realistic model for a macromolecule, and therefore it has been finding increased use in polymer science, particularly in connection with the calculation of rheological properties. The equilibrium configurational distribution function is derived (not a “random-walk” function). Then some of the recent uses of the Kramers chain for understanding the nonequilibrium properties of solutions and melts are summarized.
Keywords:Bubble growth  Multicomponent gas bubbles
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