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Solid–Liquid Equilibrium (SLE) for Polyhydric Alcohol + Cs2SO4 + H2O Ternary Systems at Different Temperatures
Authors:Rui Xiong  Dandan Zhao  Quanguo Zhai  Yucheng Jiang
Affiliation:Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an, Shaanxi, P.R. China
Abstract:The solubility, density, and refractive index data for 1,2-propanediol + Cs2SO4 + H2O, ethylene glycol + Cs2SO4 + H2O, and glycerin + Cs2SO4 + H2O ternary systems were determined at 15°C, 25°C, and 35°C. In all cases, the solubility of Cs2SO4 in aqueous solutions decreased significantly due to the presence of the polyhydric alcohol. The experimental density, refractive index, and solubility data of saturated solutions for these systems were correlated using polynomial equations. Furthermore, the refractive index and density of unsaturated ternary solutions were also determined and correlated with salt concentrations and proportions of polyhydric alcohol in these systems.
Keywords:Cs2SO4  Polyhydric alcohol  Solid–liquid equilibrium  Ternary system
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