New Environment-Friendly Approach for Bastnasite Metallurgic Treatment (Ⅰ): Extraction of Tetravalent Cerium from Sulphuric Acid Medium with Di(2-ethylhexyl) Phosphoric Acid |
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引用本文: | 朱兆武,赵娜,龙志奇,李德栋,崔大立,张国成.New Environment-Friendly Approach for Bastnasite Metallurgic Treatment (Ⅰ): Extraction of Tetravalent Cerium from Sulphuric Acid Medium with Di(2-ethylhexyl) Phosphoric Acid[J].中国稀土学报(英文版),2005,23(2):178-182. |
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作者姓名: | 朱兆武 赵娜 龙志奇 李德栋 崔大立 张国成 |
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作者单位: | AdvancedMaterialsCo.Ltd.ofBeijingGeneralResearchInstituteofNonferrousMetals,Beijing100088,China |
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摘 要: | The extraction of cerium (Ⅳ) from sulphuric acid medium with Di(2-ethylhexyl) phosphoric acid (DEHPA) was studied. The influence of sulphate ion, acidity, extractant concentration as well as the presence of fluoride ion on the extraction of Ce(Ⅳ) was investigated, and the extraction mechanism was also discussed. The results show that sulphate ion can inhibit the extraction of Ce(Ⅳ) significantly due to its complexation with Ce(Ⅳ). Fluoride ion can enhance Ce(Ⅳ) extraction dramatically by the formation of CeF2^2 and less amount of CeF^3 which can almost be extracted completely. Nevertheless, in the case as F/Ce(mole ratio) in the initial aqueous phase is approximately more than 1.5, the precipitate will be formed and the extraction can not be progressed smoothly.
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关 键 词: | 铈 稀土元素 溶剂萃取 DEHPA 乙基已基磷酸 |
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