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NiO/龙舌兰衍生多孔碳复合材料的制备及电化学性能
引用本文:邹 毓,周跃云.NiO/龙舌兰衍生多孔碳复合材料的制备及电化学性能[J].包装学报,2024,16(3):45-51.
作者姓名:邹 毓  周跃云
作者单位:湖南工业大学 醴陵陶瓷学院 湖南工业大学 城市与环境学院
摘    要:先采用水热法再经过煅烧处理,将氧化镍均匀负载到龙舌兰多孔碳上。采用X射线衍射(XRD)、扫描电镜(SEM)、红外辐射检测等,对NiO/龙舌兰衍生多孔碳复合材料(NiO/C)的结构和形貌进行表征,并通过循环伏安和充放电测试对NiO/C的电化学性能进行研究。结果表明:NiO/C-2具有优秀的能量密度与循环稳定性,在5 A/g的电流密度下,能量密度可达22 W·h/kg;循环10 000次后,容量保持率高达91%。此外,当电流密度为1 A/g时,NiO/C-2的比电容为312 F/g;当电流密度增大到20 A/g时,比电容仍高达155 F/g 。因此,基于龙舌兰多孔碳的结构稳定性,适量的NiO负载可以提升材料的比电容和循环稳定性。

关 键 词:龙舌兰  氧化镍  超级电容器  生物质衍生碳
收稿时间:2023/10/18 0:00:00

Preparation of NiO/ Agave-Derived Porous Carbon Composites and Their Electrochemical Properties
ZOU Yu,ZHOU Yueyun.Preparation of NiO/ Agave-Derived Porous Carbon Composites and Their Electrochemical Properties[J].Packaging Journal,2024,16(3):45-51.
Authors:ZOU Yu  ZHOU Yueyun
Abstract:The nickel oxide was uniformly loaded onto the agave porous carbon by hydrothermal method and then by calcination treatment. The structure and morphology of the nickel oxide/agave-derived porous carbon composites were characterized by X-Ray Diffraction, Scanning Electron Microscope and Infrared Radiation. Furthermore, electrochemical properties of the nickel oxide/agave porous carbon composites were investigated by cyclic voltammetry test and charge-discharge test. The results show that NiO/C-2 has excellent property in energy density and cycling stability, exhibiting energy density of 22 W·h/kg and capacity retention of 91% after 10 000 cycles at a current density of 5 A/g. The specific capacitance of NiO/C-2 is 312 F/g at a current density of 1 A/g, and the capacity is still as high as 155 F/g when the current density is increased to 20 A/g. Therefore, based on the structural stability of agave porous carbon, the appropriate amount of NiO loading can enhance the capacity and cycling stability of the material.
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