| 5,5′-偶氮四唑过渡金属含能配合物对RDX和HMX热分解行为的影响 |
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| 引用本文： | 焦宝娟,晏志军,陈三平.5,5′-偶氮四唑过渡金属含能配合物对RDX和HMX热分解行为的影响[J].火炸药学报,2012,35(3):52-55. |
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| 作者姓名： | 焦宝娟 晏志军 陈三平 |
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| 作者单位： | 1. 西安文理学院化学与化学工程学院,陕西西安,710065
2. 西北大学化学与材料科学学院合成与天然功能分子化学教育部重点实验室,陕西西安,710069 |
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| 摘 要： | 用DSC研究了5种5,5′-偶氮四唑过渡金属配合物MATZ(H2O)n(M=Mn,Ni,Zn,n=6;M=Co,Pb,n=3;ATZ=5,5′-偶氮四唑离子)对RDX和HMX热分解行为的影响。用分解峰温、热爆炸临界温度等特征参数评价了含配合物的二元混合物与纯组分的热分解行为。结果表明,配合物对RDX的影响大于对HMX的。含配合物的二元混合物的热分解行为与纯组分的热分解行为类似,配合物的分解影响了RDX和HMX的热分解特征参数。
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| 关 键 词： | 物理化学 含能配合物 燃速催化剂 热分解 |
Effects of Transition Metal 5,5'-Azoterazolate Energetic Complexes on Thermal Decomposition Behaviours of RDX and HMX |
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| JIAO Bao-juan
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YAN Zhi-jun
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CHEN San-ping.Effects of Transition Metal 5,5'-Azoterazolate Energetic Complexes on Thermal Decomposition Behaviours of RDX and HMX[J].Chinese Journal of Explosives & Propellants,2012,35(3):52-55. |
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| Authors: | JIAO Bao-juan YAN Zhi-jun CHEN San-ping |
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| Affiliation: | 1.Department of Chemistry and Chemical Engineering,Xi′an University of Arts and Science,Xi′an 710065,China;2.Key Laboratory of Synthetic and Natural Functional Molecule Chemistry,Ministry of Education;College of Chemistry and Materials Science,Northwest University,Xi′an 710069,China) |
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| Abstract: | The effects of five transition metal 5,5′-azoterazolate energetic complexes MATZ(H2O)n(M=Mn,Ni,Zn,n=6;M=Co,Pb,n=3;ATZ=5,5′-azoterazolate)act on the thermal decomposition behaviors of RDX and HMX were investigated with DSC technique.The thermal behaviours of pure RDX and HMX,and binary mixture were evaluated using characteristic parameters,such as maximum decomposition peak temperature and critical temperature of thermal explosion.Results showed that the effect of the complexes to RDX was notable to that of HMX,the thermal decomposition behavior of mixture was similar to that of RDX and HMX,and the characteristic parameters of RDX and HMX were influenced by the decomposition of complex. |
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| Keywords: | physical chemistry energetic complex combustion catalyst thermal decomposition |
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