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Hydrogen production from catalytic steam reforming of biomass pyrolysis oil or bio-oil derivatives: A review
Affiliation:1. Faculty of Chemical and Process Engineering Technology, College of Engineering Technology, Universiti Malaysia Pahang, 26300, Gambang, Kuantan, Pahang, Malaysia;2. Centre of Excellence for Advanced Research in Fluid Flow, Universiti Malaysia Pahang, 26300, Gambang, Kuantan, Pahang, Malaysia;3. School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia (UTM), 81310 UTM, Johor Bahru, Johor, Malaysia;4. Centre of Hydrogen Energy, Institute of Future Energy, Universiti Teknologi Malaysia (UTM), 81310 UTM, Johor Bahru, Johor, Malaysia;5. Centre for Advanced Materials and Renewable Resources, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM, Bangi, Selangor, Malaysia;1. School of Materials Science and Engineering, University of Jinan, Jinan 250022, China;2. Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yan′an University, China;3. College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China;4. School of Energy and Power Engineering, Jiangsu University, Jiangsu 212013, China;1. Chemical Institute, Universidade Federal de Goiás - UFG, Campus Samambaia, CP 131, 74001-970, Goiânia, GO, Brazil;2. Department of Chemical Engineering, Universidade Tecnológica Federal Do Paraná - UTFPR, Av. Dos Pioneiros 3131, 86036-370, Londrina, PR, Brazil;1. Chemical Engineering Department, University of the Basque Country, P. O. Box 644, 48080, Bilbao, Spain;2. Catalysis Engineering/ChemE/TUDelft, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands;1. Centre of Hydrogen Energy, Institute of Future Energy, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia;2. Department of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia;3. Centre for Sustainable Nanomaterials (CSNano), Department of Chemistry, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
Abstract:Steam reforming of biomass pyrolysis oil or bio-oil derivatives is one of the attractive approaches for hydrogen production. The current research focused on the development of promising catalysts with favorable catalytic activity and high coke resistance. Noble metal such as Rh has been proven to achieve promising reforming reaction efficiencies. However, Ni has attracted considerable attention owing to its stability, cost effectiveness, and good activity in breaking C–C and C–H bonds. Nevertheless, Ni-based catalysts have serious carbon deposition problems arising from chemical poisoning, metal sintering, and poor metal dispersion. This paper attempted to review the current trends in catalyst development considering the aspects of supports, metals, and promoters as an effort to find possible solutions for the limitations of Ni-based catalysts. The present review also covered the current understanding on the reaction mechanisms as well as the future prospects in the field of steam reforming catalysts.
Keywords:Steam reforming  Hydrogen  Heterogeneous catalysts  Bio-oil
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