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Effect of the acid type on clinoptilolite-rich tuff for hydrogen storage
Affiliation:1. Eskisehir Technical University, Faculty of Science, Department of Physics, Yunusemre Campus, 26470 Tepebasi, Eskisehir, Turkey;2. Central Research Laboratory, Eskisehir Osmangazi University, Eskisehir, Turkey;1. Department of Nuclear, Plasma, and Radiological Engineering, University of Illinois at Urbana Champaign, Urbana, IL, 61801, United States;2. Department of Mechanical Engineering, Jordan University of Science and Technology, P.O.Box 3030, Irbid, 22110, Jordan;1. National Engineering Research Center of Nonferrous Metals Materials and Products for New Energy, GRINM Group Co., Ltd., Beijing, 100088, China;2. GRIMAT Engineering Institute Co., Ltd., Beijing, 101407, China;1. Escuela de Ingeniería Bioquímica, Pontificia Universidad Católica de Valparaíso, Av. Brasil, 2085, Valparaíso, Chile;2. Aix Marseille University, Univ Toulon, CNRS, IRD, Mediterranean Institute of Oceanography, MIO UM 110, 13288, Marseille, France;3. LBE, Univ Montpellier, INRA, Narbonne, France
Abstract:Clinoptilolite from Gördes (Turkey) was treated with HCl, HNO3 and H2SO4 solutions of varying concentrations (from 2.0 M to 6.0 M) at 90 °C for 4 h to evaluate its potential for possible applications in hydrogen storage. X-ray diffraction, X-ray fluorescence and nitrogen adsorption techniques were applied for characterization of the zeolites. Hydrogen adsorption capacities of clinoptilolite samples were found in the range between 1.609 and 2.391 mmol/g. The effects of the acid modification process on the structure and hence hydrogen adsorption was evaluated according to the obtained results.
Keywords:Adsorption  Clinoptilolite  Hydrogen  XRD  XRF
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