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Kinetics of Glass Transition and Crystallization in Carbon Nanotube Reinforced Mg-Cu-Gd Bulk Metallic Glass
作者姓名:王银春  王育人  魏炳忱  李维火  孙玉峰
作者单位:[1]Institute of Mechanics, Chinese Academy of Sciences, Beijing 100080, China [2]Research Center for Materials, Department of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, China
基金项目:中国科学院知识创新工程项目,中国科学院资助项目
摘    要:Mg65Cu25Gd10 bulk metallic glass and its carbon nanotube reinforced composite were prepared. Differential scanning calorimeter (DSC) was used to investigate the kinetics of glass transition and crystallization processes. The influence of CNTs addition to the glass matrix on the glass transition and crystallization kinetics was studied. It is shown that the kinetic effect on glass transition and crystallization are preserved for both the monothetic glass and its glass composite. Adding CNTs in to the glass matrix reduces the influence of the heating rate on the crystallization process. In addition, the CNTs increase the energetic barrier for the glass transition. This results in the decrease of GFA. The mechanism of the GFA decrease was also discussed.

关 键 词:金属玻璃  碳纳米管  玻璃相变  晶化  动力学    稀土
文章编号:1002-0721(2006)03-0327-05
收稿时间:2005-04-06
修稿时间:2005-06-25

Kinetics of Glass Transition and Crystallization in Carbon Nanotube Reinforced Mg-Cu-Gd Bulk Metallic Glass
Yinchun , Yuren Wang, Bingchen Wei, Weihuo Li,Yufeng Sun.Kinetics of Glass Transition and Crystallization in Carbon Nanotube Reinforced Mg-Cu-Gd Bulk Metallic Glass[J].Journal of Rare Earths,2006,24(3):327-331.
Authors:Yinchun  Yuren Wang  Bingchen Wei  Weihuo Li  Yufeng Sun
Affiliation:aInstitute of Mechanics, Chinese Academy of Sciences, Beijing 100080, China;bResearch Center for Materials, Department of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, China
Abstract:Mg65Cu25Gd10 bulk metallic glass and its carbon nanotube reinforced composite were prepared. Differential scanning calorimeter (DSC) was used to investigate the kinetics of glass transition and crystallization processes. The influence of CNTs addition to the glass matrix on the glass transition and crystallization kinetics was studied. It is shown that the kinetic effect on glass transition and crystallization are preserved for both the monothetic glass and its glass composite.Adding CNTs in to the glass matrix reduces the influence of the heating rate on the crystallization process. In addition, the CNTs increase the energetic barrier for the glass transition. This results in the decrease of GFA. The mechanism of the GFA decrease was also discussed.
Keywords:metallic glass  carbon nanotube  glass transition  crystallization  kinetic effect  composite glass  Gadolinium  rare earths
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